Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ2O1,O2)cobaltate(II) dihydrate: an ion-pair complex
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Bis(N,N′-dimethylethylenediammonium) tris(oxalato-κ2 O 1,O 2)cobaltate(II) dihydrate: an ion-pair complex
The Co(II) ion in the title complex, (C(4)H(14)N(2))(2)[Co(C(2)O(4))(3)]·2H(2)O, is coordinated by three oxalate ions, resulting in a distorted octa-hedral geometry. Two uncoordinated water mol-ecules are present in asymmetric unit. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds between the different entities stabilize the crystal structure.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811031357